Fa'ata'apeina ma Fa'ata'apeina Fa'agasologa o Fa'asa'o Mu'a Mausalī ile Polyurethane AB Adhesive System
Mo le faʻamavaeina / faʻasalalauina o faʻamaʻi afi mumu e pei o le alumini hypophosphite (AHP), alumini hydroxide (ATH), zinc borate, ma le melamine cyanurate (MCA) i totonu o le polyurethane AB faʻapipiʻi faʻapipiʻi, o laasaga autu e aofia ai le muaʻi togafitia, faʻasolosolo faʻasolosolo, ma le faʻatonutonuina o le susu. O loʻo i lalo le faʻamatalaga auiliili (mo faʻamaufaʻailoga maualuga afi; isi faʻasologa e mafai ona fetuunai e tusa ai).
I. Mataupu Faavae Autu
- O le "Fa'ata'apeina" o le ta'apeina lea: E tatau ona fa'asalalau solo i totonu ole polyol (A-vaega) e fa'atupu ai se taofi mau.
- Fa'ata'ita'iga muamua o mea e fa'aluma ai le mu: Fa'atalanoaina fa'afitauli o le susū, fa'aputu'e, ma le fa'agaoioiga i le isocyanates.
- Fa'aopoopo fa'agasologa: Fa'aopoopo meafaitino i le fa'asologa o le mafiafia ma le lapopo'a e 'alofia ai fa'aputuga maualuga.
- Faʻasaʻo le susu: E faʻaumatia e le vai le isocyanate (-NCO) i le B-vaega, e taʻitaʻia ai le le lelei o le fofo.
II. Au'ili'iliga o Fa'atinoga (Fa'avae ile 100 vaega polyol ile A-vaega)
Laasaga 1: Fa'ata'ita'iga Mu'amu (24 itula muamua atu)
- Aluminium Hypophosphite (AHP, 10 vaega):
- Fa'apipi'i fa'alava i luga ole so'o fa'apipi'i silane (KH-550) po'o so'o fa'apipi'i titanate (NDZ-201):
- Faafefiloi 0.5 vaega so'o fa'atasi + 2 vaega anhydrous ethanol, fa'aoso mo le 10 min mo le hydrolysis.
- Fa'aopoopo le pauta AHP ma fa'aoso i le saoasaoa maualuga (1000 rpm) mo le 20 min.
- Fa'ago i totonu o le ogaumu i le 80 ° C mo le 2 itula, ona teu ai lea o fa'amaufa'ailoga.
- Fa'apipi'i fa'alava i luga ole so'o fa'apipi'i silane (KH-550) po'o so'o fa'apipi'i titanate (NDZ-201):
- Aluminium Hydroxide (ATH, 25 vaega):
- Fa'aaogā le lapopo'a fa'alalo-micron, le ATH fa'aliliu silane (fa'ata'ita'iga, Wandu WD-WF-20). Afai e le suia, fai tutusa ma le AHP.
- MCA (6 vaega) & Zinc Borate (4 vaega):
- Fa'amago i le 60°C mo le 4 itula e aveese ai le susu, ona fa'amamago lea ile mata 300-mesh.
Laasaga 2: A-Itu (Polyol Itu) Faʻasalalauga Faʻasologa
- Faafefiloi faavae:
- Fa'aopoopo le 100 vaega o le polyol (fa'ata'ita'iga, polyether polyol PPG) i se koneteina mago.
- Fa'aopoopo i ai vaega e 0.3 polyether-modified polysiloxane fa'avasegaina (eg, BYK-333).
- Fa'ata'apeina Mua'i Saosaoa maualalo:
- Fa'aopoopo mea fa'afefe mu i le fa'asologa: ATH (25 vaega) → AHP (10 vaega) → zinc borate (4 vaega) → MCA (6 vaega).
- Fa'aoso i le 300-500 rpm mo le 10 minute se'ia leai se pauta mago o totoe.
- Taape maualuga-Sili:
- Su'e i se fa'asalalau maualuga (≥1500 rpm) mo le 30 min.
- Pulea le vevela ≤50°C (ia puipuia le polyol oxidation).
- Oli ma Fa'amama (Tino!):
- Fa'asolo ile tolu-roll mill po'o le ato oneone 2-3 taimi seia o'o ile fineness ≤30μm (fa'ata'ita'i ile fua Hegman).
- Su'ega Viscosity & Defoaming:
- Fa'aopoopo i ai vaega e 0.5 o le hydrophobic fumed silica (Aerosil R202) e taofia ai le fa'amaua.
- Fa'aopoopo 0.2 vaega silicone defoamer (fa'ata'ita'iga, Tego Airex 900).
- Fa'aoso i le 200 rpm mo le 15 minute mo le fa'amama.
Laasaga 3: B-Component (Isocyanate Itu) Togafitiga
- Fa'aopoopo 4-6 vaega mole mole sieve (eg, Zeochem 3A) i le B-vaega (fa'ata'ita'iga, MDI prepolymer) mo le susū miti.
- Afai e fa'aoga vai phosphorus fa'aluma afi (filifiliga maualalo-viscosity), fa'afefiloi sa'o i le B-vaega ma fa'aoso mo le 10 min.
La'asaga 4: Fa'afefiloi ma Fa'amālōlōina
- Fuafuaga fa'afefiloi: Mulimuli i le mamanu fa'apipi'i muamua AB (fa'ata'ita'iga, A:B = 100:50).
- Faiga fa'afefiloi:
- Fa'aaogā se mea fa'afefiloi paneta e lua-vaega po'o se fa'agaau fa'afefiloi.
- Fa'afefiloi mo le 2-3 min seia o'o i le togiga (leai se manoa).
- Tulaga fa'amalolo:
- Fa'amalologa o le vevela o le potu: 24 itula (fa'aopoopo i le 30% ona o le fa'afefe o le vevela o le afi).
- Fa'ato'a fa'avaveina: 60°C/2 itula (fa'amaonia mo taunu'uga e leai ni pulu).
III. Fa'atonuga Fa'atonu Fa'atonu
| Fa'alavelave | Fofo | Metotia Su'ega |
|---|---|---|
| AHP susū mitiia/fa'aputu | Silane coating + mole mole sieve | Karl Fischer su'esu'e susū (≤0.1%) |
| ATH fa'amautu | Hydrophobic silica + tolu-roll milling | 24-itula tu'u su'ega (leai se fa'avasegaga) |
| MCA fa'agesegese fofo | Fa'atapula'a le MCA ile ≤8 vaega + fa'atuputeleina le vevela ile 60°C | Su'ega fa'agogo (≤40 min) |
| Zinc borate mafiafia | Fa'aaogā le pa'u ma'a maualalo (fa'ata'ita'iga, Firebrake ZB) | Viscometer (25°C) |
IV. Metotia Fa'ata'apeina Su'i (E aunoa ma Meafaigaluega olo)
- Togafitiga ole polo:
- Faafefiloi mea mumu ma polyol i le fua faatatau 1:1, ili polo mo le 4 itula (polo zirconia, 2mm le tele).
- Masterbatch metotia:
- Saunia se masterbatch e 50% e taofia ai le mu (polyol e ave ai), ona fa'asusu lea a'o le'i fa'aogaina.
- Fa'asalalauina ole Ultrasonic:
- Fa'aaoga le ultrasonication (20kHz, 500W, 10 min) i le slurry muamua (talafeagai mo vaega laiti).
V. Fautuaga mo le Fa'atinoga
- Faʻataʻitaʻiga laʻititi muamua: Suʻega faʻatasi ma le 100g o le A-vaega, taulaʻi i le mautu viscosity (24h suiga <10%) ma faʻamalolo vave.
- Tulafono fa'aopoopo fa'aopoopo e mumu mu:
- “Mua mamafa muamua, mama mulimuli ane; lelei muamua, mānoanoa mulimuli ane” → ATH (mamafa) → AHP (lelei) → zinc borate (medium) → MCA (mamā/maofa).
- Fa'alavelave fa'afuase'i:
- Fa'atupu fa'afuase'i le viscosity: Fa'aopoopo le 0.5% propylene glycol methyl ether acetate (PMA) e fa'afefe ai.
- Le lelei le fofoina: Fa'aopoopo le 5% MDI ua suia (eg, Wanhua PM-200) i le B-vaega.
Taimi meli: Iuni-23-2025